Polymer Design and Reaction

In Polymer Chemistry, Polymerization is a process in which relatively small molecules, called monomers, combine chemically to produce a very large chainlike or network molecule, called a polymer. The two major types of polymerization are addition polymerization and condensation polymerization. Polymerization reactions proceed via either cationic or free-radical mechanisms. This process occurs via a different reaction mechanism depending on functional groups present in reacting compounds and its steric hindrance. Stable molecules like alkenes due to sigma bonding between its carbon atoms, form polymers through relatively simple radical reactions; in contrast to those that involve complex synthesis  due to substitution at the carbonyl group of reacting molecules.

 

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