Stereo chemistry of Polymers

When a polymer has stereo chemical isomerism within the chain, its properties often depend on the stereo chemical structure. Thus the analysis of the Stereo-Chemistry of polymers is important and NMR spectroscopy has been the most valuable tool for this purpose. It is a general rule that for a polymer to crystallize, it must have highly regular polymer chains. Highly irregular polymers are almost inevitably amorphous. Polymer chains can have isomeric forms that decrease the regularity of the chains.

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